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By Maximino Manzanera
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Good reaction conversions were obtained at mild temperature (70°C) and pressure (60bar), opening possibilities to manipulate process variables as well as reactor configurations towards reaching acceptable yields. Rathore & Madras (2007) investigated the synthesis of biodiesel from edible (palm oil, groundnut oil) and non-edible oils (Pongamia pinnata and Jatropha curcas) in supercritical methanol and ethanol without using any catalyst from 200 to 400°C at 200bar. Very high conversions (>80%) were obtained within 10min and nearly complete conversions were obtained after 40min.
Multi-Feed-Stock-Biodiesel:The Modern & Profitable FAME. Production Plant, Proceeding of International Liquid Biofuels Congress. , Arishtirova, K. & Vassilev, S. (2001). MgO/NaX zeolite as basic catalyst for oxidative methylation of toluene with methane. Applied Catalysis A: General. Vol. 210, No. p. E. M. (2006). Fast, easy preparation of biodiesel using microwave heating. 20, No. p. , Wang, Y. & Zhu, S. (2007). Transesterification of soybean oil to biodiesel using SrO as a solid base catalyst, Catalysis Communications, Vol.
2008b). A wide variety of feedstock is expected to be used in Brazil for biodiesel production. ) (Agência Nacional do Petróleo, Gás Natural e Biocombustíveis, 2011). , 2010). , 2009). Fats and oils of differing origin have different fatty acid compositions (Table 1). The properties of fats and oils, and hence their commercial value, depend on the fatty acid composition and of the triacylglycerol structure (Sheldon, 1996). e. myristic, palmitic, stearic acids) rises An Overview of Enzyme-Catalyzed Reactions and Alternative Feedstockfor Biodiesel Production 29 turbidity and the cetane number, decreases NOx emissions, and shows better stability.
Alternative Fuel by Maximino Manzanera